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Carbon traps offer a solution for the removal of undesirable gaseous
and vapour contaminants in glove boxes. The unique physical absorptive
properties of activated carbon make this an ideal, and economical,
consumable product for the removal of solvents. Impregnated activated
carbons function by the combined effect of chemical reaction and
adsorption to remove contaminants that are not readily adsorbed
by activated carbon alone.
Carbon traps can be installed in the outlet vents of gas purged
(open loop) glove boxes, and in line prior to the gas purifier in
gas recirculated (closed loop) glove boxes. Carbon traps should
not be used in place of a particulate filter but in conjunction
with one, as each has a dedicated design and operational function.
Gas purifiers are particularly vulnerable to being de-activated
(poisoned) by sulphur and sulphur compounds, halides, chlorides,
halogen, alcohols, hydrazine, phosphene, arsine, arsenate, mercury
and other metallic compounds. Solvents have an adverse effect on
the moisture reactant.
Carbon traps need to be carefully selected to the design parameters
of the glove box gas flow velocity and volume for effective operation.
Additionally, the carbon capacity needs to reflect the amount of
contaminant and recharge time scale if saturation, and contaminant
bypass, is to be avoided.
In practical terms it is difficult to predict the life or monitor
the condition of a carbon filter in glove box applications. Activated
carbon has a variable weight of absorbed contaminant to weight of
carbon, with ratios of 1% up to 50% for differing chemicals. As
a consequence of this a cautious over-design approach should be
taken.
Glove Box Technology Ltd offers three basic designs, with carbon
capacities of 1 litre, 5 litres and 8 litres. The 1 litre unit is
for small glove boxes with low gas flow rates and small quantities
of contaminants. The 5-litre unit is designed for general use in
gas purged (open loop) or gas recirculated (closed loop) glove boxes
with moderate quantities of contaminant. And the 8-litre unit is
designed for harsh conditions in gas recirculated (closed loop)
glove boxes.
The 1 litre unit is available in stainless steel, as an in-line
trap with ½" BSP connections to either end, or in "open"
ended design for connection to either a ½" BSP or NW16
outlet. The carbon charge is not included but can be supplied under
separate instruction to customer requirements.
The 5-litre unit is available in stainless steel as an in-box trap
and features an integrated inline HEPA filter. Connection to the
glove box gas outlet (open loop) or gas recirculation system (closed
loop) is through a NW40 outlet to the side of the carbon trap. Designed
for removal through the glove box antechamber, the carbon trap should
first be double bagged (PVC) and sealed with a cable tie prior to
transfer to a fume cabinet for recharge. Recharge carbon must be
oven dried prior to refill and must be dust free granular quality.
The carbon charge is not included but can be supplied under separate
instruction to customer requirements.
The 8-litre unit is available in stainless steel, as a self-contained
floor mounted unit and is designed as a "break in" trap
for fitting prior to the gas purifier using NW40 connections. Features
an arrangement of 5 full bore stainless steel ball valves, three
for permanent installation in the gas recirculation line to provide
a gas bypass facility, and two permanently with the carbon trap,
for isolating prior to removal to a fume cupboard for a carbon recharge.
Additionally equipped with a compound gauge, and double valve quick
disconnect for pluming into the vacuum line to remove air and trace
moisture from the recharged and installed carbon trap. Recharge
carbon must be oven dried prior to refill and must be dust free
granular quality. The carbon charge is not included but can be supplied
under separate instruction to customer requirements.
All carbon traps are designed on typical glove box gas flow velocity
and volume rates to provide dwell times consistent with the removal
of contaminants from our recommended carbon granule size with low
gas pressure drop. Carbon capacity is based upon our experience
of average duty requirements, and an annual service recharge to
optimise filter efficiency and replacement economy.
Custom designed carbon traps can be of an integrated design or
stand-alone units for installation into existing glove boxes. Large
carbon traps are supplied with carbon filter racks equipped with
safe change facilities.
© GLOVE BOX TECHNOLOGY LTD January 2004
Treatable Contaminants
Substances suffixed by a * require special treatment
| Acetic acid |
Acetic anhydride |
| Acetone |
Acids |
| Acrolein |
Acrylic acid |
| Acrylonitrile |
Adhesives |
| Alcohol |
Allyl alcohol |
| Amines* |
Ammonia* |
| Amyl acetate |
Amyl alcohol |
| Amyl ether |
Aniline |
| |
|
| Benzene |
Bromine |
| Butadiene |
Butyl acetate |
| Butyl alcohol |
Butyl cellosolve |
| Butyl chloride |
Butyl ether |
| Buryraldehyde |
Butyric acid* |
| |
|
| Camphor |
Caprylic acid* |
| Carbolic acid* |
Carbon disulphide |
| Carbon tetrachloride |
Cellosolve (Ethyl Glycol) |
| Cellosolve acetate |
Chlorine |
| Chlorobenzene |
Chlorobutadiene |
| Chloroform |
Chloro nitropropane |
| Chloropicrin |
Chlorothene |
| Corrosive gases* |
Cresol |
| Crotonaldehyde |
Cyclohexane |
| Cyclohexanol |
Cyclohexanene |
| Cyclohexene |
|
| |
|
| Decane |
Dibromoethane |
| Dichlorobenzene |
Dichlorodifluoromethane |
| Dichloroethane |
Dichloroethylene |
| Dichloroethyl ether |
Dichloromonofluoromethane |
| Dichloro-nitroethane |
Dichloropropane |
| Dichlorotetrafluoroethane |
Diethyl amine |
| Diethyl ketone |
Dimethylaniline |
| Dimethylsulphate |
Dipentane |
| Dioxane |
Dipropyl ketone |
| |
|
| Ether |
Ethyl acetate |
| Ethyl acrylate* |
Ethyl alcohol |
| Ethylamine |
Ethyl benzene |
| Ethyl bromide |
Ethyl chloride |
| Ethyl ether |
Ethyl formate |
| Ethyl mercaptan |
Ethyl silicate |
| Ethylene chlorhydrin |
Ethylene dichloride |
| Ethylene oxide |
|
| |
|
| Fluorotrichloromethane |
Formaldehyde* |
| Formic acid |
Freons |
| |
|
| Genklene |
Glutaraldehyde |
| |
|
| Heptane |
Heptylene |
| Hexane |
Hexylene (1-Hexane) |
| Hexyne (Butyl acetylene) |
Hydrogen bromide* |
| Hydrogen chloride* |
Hydrogen cyanide |
| Hydrogen fluoride* |
Hydrogen iodide* |
| Hydrogen selenide |
Hydrogen sulphide* |
| |
|
| Indole |
Iodine |
| Iodoform |
Isocyanates |
| Isoprene |
Isopropyl acetate |
| Isopropyl alcohol |
Isopropyl ether |
| |
|
| Lactic acid |
|
| |
|
| Mercaptans* |
Mercury* |
| Mesityl oxide |
Methyl acetate |
| Methyl acrylate |
Methyl alcohol |
| Methyl bromide |
Methyl butyl ketone |
| Methyl cellosolve |
Methyl cellosolve acetate |
| Methyl chloroform |
Methyl ether |
| Methyl isobutyl ketone |
Methyl formate |
| Methyl mercaptan* |
Methylal |
| Methylcyclohexane |
Methylcyclohexanol |
| Methylcyclohexanone |
Methylene chloride |
| Monochlorobenzene |
Monofluorotrichloromethane |
| |
|
| Napthalene |
Nicotine |
| Nitric acids* |
Nitric Oxides* |
| Nitrobenzenes |
Nitroethane |
| Nitroglycerine |
Nitromethane |
| Nitropropane |
Nitrotoluene |
| Nonane |
|
| |
|
| Octalene |
Octane |
| Organic chemicals |
Ozone |
| |
|
| Paradichlorobenzene |
Pentane |
| Pentanone |
Pentylene |
| Pentyne |
Perchloroethylene |
| Phenol |
Phosgene |
| Plastics |
Plasticisers |
| Poison gases* |
Propanol |
| Propionaldehyde |
Propionic acid |
| Propyl acetate |
Propyl alcohol |
| Propyl chloride |
Propyl ether |
| Pyridine |
|
| |
|
| Radiation products* |
Rubbers |
| |
|
| Skatole |
Solvents |
| Stoddard solvent |
Styrene monomer |
| Sulphur compounds* |
Sulphur dioxide* |
| Sulphur trioxide |
Sulphuric acid* |
| |
|
| Tarnishing gases |
Tetrachloroethane |
| Tetrachloroethylene |
Toluene |
| Toluene di isocyanate |
Toluidine |
| Trichloroethylene |
|
| |
|
| Urea |
Uric acid* |
| |
|
| Valeric acid* |
Valericaldehyde |
| Vinyl chloride |
Vinyl chloride/acetate |
| |
|
| Wood alcohol |
|
| |
|
| Xylene |
|
This list is not exhaustive and if a particular compound does not
appear, please contact our technical sales department for further
advice.
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